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双{μ-N'-[1-(5-溴-2-氧化苯基)亚乙基]苯磺酰肼基}-κO,N':N;κN:O,N'-双-[(二甲亚砜-κO)铜(II)]

Bis{μ-N'-[1-(5-bromo-2-oxidophen-yl)ethyl-idene]benzene-sulfono-hydrazidato}-κO,N':N;κN:O,N'-bis-[(dimethyl sulfoxide-κO)copper(II)].

作者信息

Ali Hapipah M, Laila Musalem, Rizal Razali M, Ng Seik Weng

机构信息

Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Jan 25;64(Pt 2):m414. doi: 10.1107/S1600536808002201.

DOI:10.1107/S1600536808002201
PMID:21201360
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2960193/
Abstract

In the title centrosymmetric dinuclear complex, [Cu(2)(C(15)H(11)BrN(2)O(3)S)(2)(C(2)H(6)OS)(2)], the Cu(II) ion is N,O-chelated by a dianionic ligand, monocoordinated by the sulfonamide N atom of a symmetry-related ligand and coordinated by an O atom from a dimethyl sulfoxide ligand, forming a distorted square-planar coordination geometry.

摘要

在标题为中心对称双核配合物[Cu₂(C₁₅H₁₁BrN₂O₃S)₂(C₂H₆OS)₂]中，Cu(II)离子由一个双阴离子配体进行N,O-螯合，由一个对称相关配体的磺酰胺N原子进行单配位，并由一个来自二甲基亚砜配体的O原子进行配位，形成扭曲的平面正方形配位几何结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cffa/2960193/8cd9435848f1/e-64-0m414-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cffa/2960193/8cd9435848f1/e-64-0m414-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cffa/2960193/8cd9435848f1/e-64-0m414-fig1.jpg

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本文引用的文献

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A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.