双{μ-N'-[1-(5-溴-2-氧化苯基)亚乙基]苯磺酰肼基}-κO,N':N;κN:O,N'-双-[(二甲亚砜-κO)铜(II)]
Bis{μ-N'-[1-(5-bromo-2-oxidophen-yl)ethyl-idene]benzene-sulfono-hydrazidato}-κO,N':N;κN:O,N'-bis-[(dimethyl sulfoxide-κO)copper(II)].
作者信息
Ali Hapipah M, Laila Musalem, Rizal Razali M, Ng Seik Weng
机构信息
Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 Jan 25;64(Pt 2):m414. doi: 10.1107/S1600536808002201.
Abstract
In the title centrosymmetric dinuclear complex, [Cu(2)(C(15)H(11)BrN(2)O(3)S)(2)(C(2)H(6)OS)(2)], the Cu(II) ion is N,O-chelated by a dianionic ligand, monocoordinated by the sulfonamide N atom of a symmetry-related ligand and coordinated by an O atom from a dimethyl sulfoxide ligand, forming a distorted square-planar coordination geometry.
摘要
在标题为中心对称双核配合物[Cu₂(C₁₅H₁₁BrN₂O₃S)₂(C₂H₆OS)₂]中，Cu(II)离子由一个双阴离子配体进行N,O-螯合，由一个对称相关配体的磺酰胺N原子进行单配位，并由一个来自二甲基亚砜配体的O原子进行配位，形成扭曲的平面正方形配位几何结构。
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