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{N'-[(E)-1-(5-溴-2-氧化苯基)亚乙基-κO]-4-甲基苯甲酰肼基-κN',O}(吡啶-κN)镍(II)

{N'-[(E)-1-(5-Bromo-2-oxidophen-yl)ethyl-idene-κO]-4-methyl-benzohydrazidato-κN',O}(pyridine-κN)nickel(II).

作者信息

Zheng Chang-Zheng, Wang Liang, Liu Juan, Wang Yu-Jie

机构信息

College of Environment and Chemical Engineering, Xi'an Polytechnic University, 710048 Xi'an, Shaanxi, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Aug 1;67(Pt 8):m1132. doi: 10.1107/S1600536811029114. Epub 2011 Jul 23.

DOI:10.1107/S1600536811029114
PMID:22090894
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3212192/
Abstract

The central Ni(II) atom in the title complex, [Ni(C(16)H(13)BrN(2)O(2))(C(5)H(5)N)], is in a square-planar trans-N(2)O(2) environment defined by the NO(2) donor atoms of the tridentate hydrazone ligand and the monodentate pyridine ligand. The pyridine mol-ecule forms a dihedral angle of 9.99 (11)° with the least-squares plane through the NiN(2)O(2) atoms.

摘要

在标题配合物[Ni(C₁₆H₁₃BrN₂O₂)(C₅H₅N)]中，中心Ni(II)原子处于由三齿腙配体的NO₂供体原子和单齿吡啶配体所定义的平面正方形反式-N₂O₂环境中。吡啶分子与通过NiN₂O₂原子的最小二乘平面形成9.99 (11)°的二面角。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c02d/3212192/91cc3ef1a627/e-67-m1132-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c02d/3212192/91cc3ef1a627/e-67-m1132-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c02d/3212192/91cc3ef1a627/e-67-m1132-fig1.jpg

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