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4-氯-N'-(2-羟基-1-萘基亚甲基)苯甲酰肼

4-Chloro-N'-(2-hydr-oxy-1-naphthyl-idene)benzohydrazide.

作者信息

Yang De-Suo

机构信息

Department of Chemistry and Chemical Engineering, Baoji University of Arts and Sciences, Baoji 721007, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Aug 16;64(Pt 9):o1759. doi: 10.1107/S1600536808025828.

DOI:10.1107/S1600536808025828
PMID:21201741
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2960590/
Abstract

The mol-ecule of the title compound, C(18)H(13)ClN(2)O(2), displays a trans configuration with respect to the C=N double bond. The dihedral angle between the benzene and naphthyl ring systems is 6.0 (2)°. An O-H⋯N hydrogen bond is observed in the mol-ecular structure. In the crystal structure, mol-ecules are linked through inter-molecular N-H⋯O hydrogen bonds and π-π stacking inter-actions [centroid-centroid distance = 3.603 (2) Å], forming chains running along the b axis.

摘要

标题化合物C(18)H(13)ClN(2)O(2)的分子相对于C=N双键呈反式构型。苯环和萘环系统之间的二面角为6.0 (2)°。在分子结构中观察到O-H⋯N氢键。在晶体结构中，分子通过分子间N-H⋯O氢键和π-π堆积相互作用[质心-质心距离 = 3.603 (2) Å]相连，形成沿b轴延伸的链。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/68e4/2960590/adcfaa7825c2/e-64-o1759-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/68e4/2960590/0fff79f604f7/e-64-o1759-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/68e4/2960590/adcfaa7825c2/e-64-o1759-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/68e4/2960590/0fff79f604f7/e-64-o1759-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/68e4/2960590/adcfaa7825c2/e-64-o1759-fig2.jpg

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