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2-氯-N'-(2-羟基-3,5-二碘亚苄基)苯甲酰肼

2-Chloro-N'-(2-hy-droxy-3,5-diiodo-benzyl-idene)benzohydrazide.

作者信息

Wang Fei, Liu Da-Yong, Wang Hai-Bo, Meng Xian-Sheng, Kang Ting-Guo

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Apr 1;67(Pt 4):o810. doi: 10.1107/S1600536811007653. Epub 2011 Mar 9.

DOI:10.1107/S1600536811007653
PMID:21754096
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3099825/
Abstract

In the title compound, C(14)H(9)ClI(2)N(2)O(2), the dihedral angle between the benzene rings is 65.9 (2)° and an intra-molecular O-H⋯N hydrogen bond generates an S(6) ring. The mol-ecule has an E conformation about the C=N bond. In the crystal, mol-ecules are linked into C(4) chains propagating in [001] by N-H⋯O hydrogen bonds.

摘要

在标题化合物C₁₄H₉ClI₂N₂O₂中，苯环之间的二面角为65.9（2）°，分子内的O—H⋯N氢键形成一个S（6）环。分子关于C=N键呈E构象。在晶体中，分子通过N—H⋯O氢键连接成沿[001]方向延伸的C（4）链。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2b9d/3099825/ac53f6e93251/e-67-0o810-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2b9d/3099825/da3141c4d6d3/e-67-0o810-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2b9d/3099825/ac53f6e93251/e-67-0o810-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2b9d/3099825/da3141c4d6d3/e-67-0o810-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2b9d/3099825/ac53f6e93251/e-67-0o810-fig2.jpg

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