（庚二酸根-κO,O'）双（1,10-菲咯啉-κN,N'）锌（II）六水合物
(Heptanedioato-κO,O')bis-(1,10-phenanthroline-κN,N')zinc(II) hexa-hydrate.
作者信息
Lin Jian-Li, Wang Yuan-Yuan
机构信息
State Key Laboratory, Base of Novel Functional Materials and Preparation Science, Institute of Solid Materials Chemistry, Faculty of Materials Science and Chemical Engineering, Ningbo University, Ningbo 315211, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 Mar 7;64(Pt 4):m527-8. doi: 10.1107/S1600536808006004.
In the crystal structure of the title compound, [Zn(C(7)H(10)O(4))(C(12)H(8)N(2))(2)]·6H(2)O, the Zn(II) atom is coordinated by two carboxyl-ate O atoms of a mono-bidentate chelating pimelate anion (pimelic acid is hepta-nedioic acid) and four N atoms of two phenanthroline ligands, forming a considerably distorted octa-hedral ZnN(4)O(2) coordination geometry. The complexes are assembled into a three-dimensional network via C-H⋯O, C-H⋯π and π-π inter-actions. The mean inter-planar distance between adjacent phenanthroline ligands is 3.399 (2) Å.
在标题化合物[Zn(C₇H₁₀O₄)(C₁₂H₈N₂)₂]·6H₂O的晶体结构中，Zn(II)原子由一个单齿螯合庚二酸根阴离子（庚二酸为庚烷二酸）的两个羧酸根O原子和两个菲咯啉配体的四个N原子配位，形成一个严重扭曲的八面体ZnN₄O₂配位几何构型。这些配合物通过C-H⋯O、C-H⋯π和π-π相互作用组装成三维网络。相邻菲咯啉配体之间的平均面间距为3.399 (2) Å。
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