链状聚[双（二甲基铵）[[氯化铜（II）]-二-μ-氯-[氯化铜（II）]-二-μ-叠氮基-κN:N]]
catena-Poly[bis(dimethylazanium) [[chloridocopper(II)]-di-μ-chlorido-[chloridocopper(II)]-di-μ-azido-κN:N]].
作者信息
Zhang Wei-Yi, Yang Li, Liu Jie
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1877-8. doi: 10.1107/S1600536811050537. Epub 2011 Nov 30.
Abstract
The crystal structure of the title complex, {(C(2)H(8)N)[CuCl(2)(N(3))]}(n), exhibits inorganic chains consisting of Cu(II) cations as well azide and chloride anions. The chains, made up from Cu-Cl-Cu-N-Cu linkages, are aligned parallel to the c axis. This architecture is further stabilized by a number of N-H⋯Cl hydrogen bonds involving the protonated charge-compensating dimethyl-amine cations and chloride atoms.
摘要
标题配合物{(C₂H₈N)[CuCl₂(N₃)]}ₙ的晶体结构显示出由Cu(II)阳离子以及叠氮化物和氯化物阴离子组成的无机链。这些由Cu-Cl-Cu-N-Cu键构成的链平行于c轴排列。这种结构通过一些涉及质子化电荷补偿二甲胺阳离子和氯原子的N-H⋯Cl氢键进一步稳定。
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