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聚[二水合-μ(2)-草酸根-二-μ(2)-嘧啶-2-羧酸根-二锰(II)]

Poly[diaqua-μ(2)-oxalato-di-μ(2)-pyrimidine-2-carboxyl-ato-dimanganese(II)].

作者信息

Rodríguez-Diéguez Antonio, Aouryaghal Hakima, Mota A J, Colacio Enrique

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Apr 2;64(Pt 5):m618. doi: 10.1107/S1600536808002687.

DOI:10.1107/S1600536808002687
PMID:21202173
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2961100/
Abstract

In the title compound, Mn(2)(C(2)O(4))(C(5)H(3)N(2)O(2))(2)(H(2)O)(2), the Mn(II) atom exhibits a distorted octa-hedral coordination geometry, with the centrosymmetric oxalate anion and the monoanionic pyrimidine-2-carboxyl-ate ligands generating a two-dimensional honeycomb network with a (6,3)-topology.

摘要

在标题化合物[Mn₂(C₂O₄)(C₅H₃N₂O₂)₂(H₂O)₂]ₙ中，Mn(II)原子呈现出扭曲的八面体配位几何构型，中心对称的草酸根阴离子和单阴离子嘧啶 - 2 - 羧酸酯配体形成了具有(6,3)拓扑结构的二维蜂窝状网络。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0021/2961100/df3602da97e6/e-64-0m618-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0021/2961100/510f4c54654a/e-64-0m618-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0021/2961100/df3602da97e6/e-64-0m618-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0021/2961100/510f4c54654a/e-64-0m618-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0021/2961100/df3602da97e6/e-64-0m618-fig2.jpg

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本文引用的文献

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Dalton Trans. 2007 May 14(18):1821-8. doi: 10.1039/b618981d. Epub 2007 Mar 21.
3
Self-assembled cationic heterochiral honeycomb-layered metal complexes with the in situ generated pyrimidine-2-carboxylato bisdidentate ligand. Hydrothermal synthesis, crystal structures, magnetic properties, and theoretical study of [M2(micro-pymca)3]OH.H2O (M = FeII, CoII).
聚[双-(μ(2)-嘧啶-2-羧基-κO,N:O',N')钙]
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Inorg Chem. 2007 Apr 2;46(7):2503-10. doi: 10.1021/ic061908e. Epub 2007 Feb 28.