Wang Yuan, Liu Zheng, Gao Jiong-Yang
Key Laboratory of Non-ferrous Metal Materials and New Processing Technology, Department of Materials and Chemical Engineering, Guilin University of Technology, Ministry of Education, Guilin 541004, People's Republic of China.
Acta Crystallogr Sect E Struct Rep Online. 2008 Apr 10;64(Pt 5):m633-4. doi: 10.1107/S1600536808008982.
In the title compound, [Cu(C(8)H(5)Cl(2)N(3)OS)(C(3)H(7)NO)]·C(3)H(7)NO, the Cu(II) atom is coordinated in a slightly distorted square-planar geometry by an O, an S and an N atom from the tridentate ligand 3,5-dichloro-salicylaldehyde thio-semi-carb-azonate ligand and one O atom from dimethyl-formamide. At the same time, the Cu atom is in contact with S and Cl atoms from another two complexes [Cu⋯S and Cu⋯Cl = 2.9791 (2) and 3.3800 (3) Å, respectively], thereby forming a [4 + 2] coordination geometry. The crystal structure exhibits N-H⋯O and N-H⋯N hydrogen bonds.
在标题化合物[Cu(C₈H₅Cl₂N₃OS)(C₃H₇NO)]·C₃H₇NO中，Cu(II)原子由三齿配体3,5 - 二氯水杨醛硫代半卡巴腙配体的一个O原子、一个S原子和一个N原子以及二甲基甲酰胺的一个O原子以略微扭曲的平面正方形几何构型配位。同时，Cu原子与另外两个配合物中的S和Cl原子接触[Cu⋯S和Cu⋯Cl分别为2.9791 (2) 和3.3800 (3) Å]，从而形成[4 + 2]配位几何构型。晶体结构呈现出N - H⋯O和N - H⋯N氢键。
