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μ-1,4-双（二苯基膦基）丁烷-κO:O']双- [环戊基-二苯基（三氟乙酸根-κO）锡（IV）]

μ-1,4-Bis(diphenyl-phosphino-yl)butane-κO:O']bis-[cyclo-pentyl-diphen-yl(trifluoro-acetato-κO)tin(IV).

作者信息

Teo Yin Yin, Lo Kong Mun, Ng Seik Weng

机构信息

Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 May 10;64(Pt 6):m790. doi: 10.1107/S1600536808013202.

DOI:10.1107/S1600536808013202
PMID:21202479
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2961610/
Abstract

The mol-ecule of the dinuclear title compound, [Sn(2)(C(5)H(9))(2)(C(6)H(5))(4)(C(2)F(3)O(2))(2)(C(28)H(28)O(2)P(2))], lies on a center of inversion at the mid-point of the central C-C bond of the bridging phosphine oxide ligand. The Sn atom is five-coordinate in a trans-C(3)SnO(2) trigonal-bipyramidal geometry.

摘要

双核标题化合物[Sn₂(C₅H₉)₂(C₆H₅)₄(C₂F₃O₂)₂(C₂₈H₂₈O₂P₂)]的分子位于桥连氧化膦配体中心C-C键中点的对称中心上。Sn原子以反式-C₃SnO₂三角双锥几何构型呈五配位。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c6f5/2961610/e7ddf8ba0d72/e-64-0m790-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c6f5/2961610/e7ddf8ba0d72/e-64-0m790-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c6f5/2961610/e7ddf8ba0d72/e-64-0m790-fig1.jpg

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本文引用的文献

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A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.