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二水合{2-[(5-溴-2-氧化苄基亚甲基)氨基-κN,O]-3-甲基戊酸根-κO}(1,10-菲咯啉-κN,N')铜(II)

{2-[(5-Bromo-2-oxidobenzyl-idene)amino-κN,O]-3-methyl-penta-noato-κO}(1,10-phenanthroline-κN,N')copper(II) dihydrate.

作者信息

Liu Zheng, Wang Yong-Liao, Wang Yuan

机构信息

Key Laboratory of Non-ferrous Metal Materials and Processing Technology, Department of Materials and Chemical Engineering, Guilin University of Technology, Ministry of Education, Guilin 541004, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 May 3;64(Pt 6):m760. doi: 10.1107/S1600536808009495.

DOI:10.1107/S1600536808009495
PMID:21202453
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2961405/
Abstract

In the title compound, [Cu(C(13)H(14)BrNO(3))(C(12)H(8)N(2))]·2H(2)O, the Cu(II) atom is penta-coordinated in a square-pyramidal geometry. The crystal packing is stabilized by O-H⋯O hydrogen bonds.

摘要

在标题化合物[Cu(C₁₃H₁₄BrNO₃)(C₁₂H₈N₂)]·2H₂O中，铜（II）原子以四方锥几何构型进行五配位。晶体堆积通过O—H⋯O氢键得以稳定。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2836/2961405/0ee17c4cf38e/e-64-0m760-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2836/2961405/2438e5166f68/e-64-0m760-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2836/2961405/0ee17c4cf38e/e-64-0m760-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2836/2961405/2438e5166f68/e-64-0m760-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2836/2961405/0ee17c4cf38e/e-64-0m760-fig2.jpg

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本文引用的文献

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A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.