Guo Ying, Cai Hua, Li Jiangang, Wan Guobao
College of Science, Civil Aviation University of China, Tianjin 300300, People's Republic of China.
Acta Crystallogr Sect E Struct Rep Online. 2008 May 7;64(Pt 6):m784. doi: 10.1107/S1600536808012609.
In the crystal structure of the title complex, Cd(N(3))(2)(C(11)H(11)N(31))(2), there are two crystallographically independent Cd(II) atoms. Both exist in an octa-hedral environment composed of four N atoms of the N(3) (-) groups and two N atoms from two monodentate 1-phenyl-3-(1H-1,2,4-triazol-1-yl)propan-1-one ligands that are positioned trans to each other. Adjacent Cd(II) centres in the crystal structure are bridged by a pair of N(3) (-) anions in a μ-1,3-fashion, forming an infinite one-dimensional array.
在标题配合物Cd(N(3))(2)(C(11)H(11)N(31))(2)的晶体结构中，有两个晶体学独立的Cd(II)原子。两者都存在于由N(3) (-)基团的四个N原子和来自两个单齿1-苯基-3-(1H-1,2,4-三唑-1-基)丙-1-酮配体的两个N原子组成的八面体环境中，这两个配体彼此反式定位。晶体结构中相邻的Cd(II)中心由一对以μ-1,3-方式的N(3) (-)阴离子桥连，形成无限的一维阵列。
