二甲基（2,2':6',2''-三联吡啶-κN,N',N''）锌（II）
Dimeth-yl(2,2':6',2''-terpyridine-κN,N',N'')zinc(II).
作者信息
Shalumova Tamila, Tanski Joseph M
机构信息
Department of Chemistry, Vassar College, Poughkeepsie, NY 12604, USA.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Oct 7;65(Pt 11):m1325. doi: 10.1107/S1600536809040136.
The title compound, [Zn(CH(3))(2)(C(15)H(11)N(3))], was synthesized by the addition of dimethyl-zinc to 2,2':6',2''-terpyridine and was crystallized by the slow evaporation of THF. The penta-coordinate Zn(II) atom, lying on a twofold rotation axis, displays a distorted trigonal-bipyramidal geometry, with two terminal N atoms at the axial positions and the central N atom and two methyl C atoms at the equatorial positions.
标题化合物[Zn(CH₃)₂(C₁₅H₁₁N₃)]通过向2,2':6',2''-三联吡啶中加入二甲基锌合成，并通过四氢呋喃的缓慢蒸发结晶。位于二重旋转轴上的五配位Zn(II)原子呈现出扭曲的三角双锥几何构型，两个末端N原子位于轴向位置，中心N原子和两个甲基C原子位于赤道位置。
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