Thampidas V S, Radhakrishnan T, Pike Robert D
Acta Crystallogr Sect E Struct Rep Online. 2008 Jul 5;64(Pt 8):m990-1. doi: 10.1107/S1600536808019715.
The title compound, [Mn(C(16)H(14)N(2)O(2))(C(7)H(4)NO(4))(H(2)O)], is a Jahn-Teller-distorted manganese(III) monomer with an octa-hedral geometry. The tetra-dentate Schiff base accommodates the Mn(III) ion at the centre of a nearly planar square. The axial positions are occupied by a monodentate carboxyl-ate group and a water mol-ecule. Adjacent monomers inter-act through hydrogen bonding between the noncoordinated C=O group of the carboxyl-ate and the coordinated water mol-ecule to produce chains extending parallel to the b axis.
标题化合物[Mn(C₁₆H₁₄N₂O₂)(C₇H₄NO₄)(H₂O)]是一种具有八面体几何构型的Jahn-Teller畸变的锰(III)单体。四齿席夫碱在近乎平面正方形的中心配位锰(III)离子。轴向位置由一个单齿羧酸根基团和一个水分子占据。相邻单体通过羧酸根未配位的C=O基团与配位水分子之间的氢键相互作用，形成平行于b轴延伸的链。
