二-μ-水合双-[二水合双(硫氰酸根-κN)铁(II)] 4-(4-氯苯基)-1,2,4-三唑六溶剂合物
Di-μ-aqua-bis-[diaqua-bis(thio-cyanato-κN)iron(II)] 4-(4-chloro-phen-yl)-1,2,4-triazole hexa-solvate.
作者信息
Li Xiuhua, Zuo Ya
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 Jul 5;64(Pt 8):m996-7. doi: 10.1107/S1600536808019326.
Abstract
The title complex, [Fe(2)(NCS)(4)(H(2)O)(6)]·6C(8)H(6)ClN(3), comprises two distorted octa-hedral iron(II) centers straddling a crystallographic inversion center and bridged by two aqua O atoms to form a quadrilateral core. The aqua O atom of the core is involved in hydrogen bonds with the triazole N atoms of the solvent mol-ecules, generating one-dimensional ladder motifs, and three inter-molecular C-H⋯S hydrogen bonds, forming a three-dimensional hydrogen-bonding network.
摘要
标题配合物[Fe₂(NCS)₄(H₂O)₆]·6C₈H₆ClN₃包含两个扭曲的八面体铁(II)中心，横跨一个晶体学反演中心，并由两个水分子的氧原子桥连形成一个四边形核心。核心中的水分子氧原子与溶剂分子的三唑氮原子形成氢键，产生一维阶梯状结构基元，以及三个分子间C—H⋯S氢键，形成三维氢键网络。
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