手性 1,2,3-三唑𬭩盐作为具有阴离子识别能力的新型阳离子有机催化剂：在手性吲哚啉酮的不对称烷基化反应中的应用。
Chiral 1,2,3-triazoliums as new cationic organic catalysts with anion-recognition ability: application to asymmetric alkylation of oxindoles.
机构信息
Department of Applied Chemistry, Graduate School of Engineering, Nagoya University, Nagoya, 464-8603, Japan.
出版信息
J Am Chem Soc. 2011 Feb 9;133(5):1307-9. doi: 10.1021/ja1102844. Epub 2011 Jan 4.
PMID:21204518
Abstract
Chiral 1,2,3-triazoliums have been designed, and the rational structural modification based on their unique anion-binding abilities has led to the establishment of the highly enantioselective alkylation of 3-substituted oxindoles.
摘要
手性 1,2,3-三唑鎓已被设计出来，基于其独特的阴离子结合能力的合理结构修饰导致了 3-取代的吲哚啉的高对映选择性烷基化反应的建立。
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