Department of Chemistry, University of Western Ontario, London, Canada N6A 5B7.
Chem Commun (Camb). 2011 Mar 14;47(10):2808-10. doi: 10.1039/c0cc05411a. Epub 2011 Jan 31.
Silver(I) salts, AgX, form self-assembled polymers with the chiral diphosphine ligand R,R-trans-C(6)H(10)(NHCO-2-C(6)H(4)PPh(2))(2), 1, of formula {Ag(2)X(2)(μ-1)}(n) and ring-opening polymerization of the trans chelate complex [Ag(1)]X has given the helical polymer [{Ag(μ-1)}(n)]X(n), when X = CF(3)SO(3).
银(I)盐,AgX,与手性双膦配体 R,R-trans-C(6)H(10)(NHCO-2-C(6)H(4)PPh(2))(2),1,形成自组装聚合物,其化学式为{Ag(2)X(2)(μ-1)}(n),并且反式螯合物 [Ag(1)]X 的开环聚合得到了螺旋聚合物 [{Ag(μ-1)}(n)]X(n),当 X = CF(3)SO(3) 时。