• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

使用噻吩并[3,4-c]吡咯-4,6-二酮和二噻吩并[3,2-b:2',3'-d]噻吩共聚物的体异质结太阳能电池，其功率转换效率为 7.3%。

Bulk heterojunction solar cells using thieno[3,4-c]pyrrole-4,6-dione and dithieno[3,2-b:2',3'-d]silole copolymer with a power conversion efficiency of 7.3%.

机构信息

Institute for Microstructural Sciences, National Research Council of Canada, Ottawa, Ontario K1A 0R6, Canada.

出版信息

J Am Chem Soc. 2011 Mar 30;133(12):4250-3. doi: 10.1021/ja200314m. Epub 2011 Mar 4.

DOI:10.1021/ja200314m
PMID:21375331
Abstract

A new alternating copolymer of dithienosilole and thienopyrrole-4,6-dione (PDTSTPD) possesses both a low optical bandgap (1.73 eV) and a deep highest occupied molecular orbital energy level (5.57 eV). The introduction of branched alkyl chains to the dithienosilole unit was found to be critical for the improvement of the polymer solubility. When blended with PC(71)BM, PDTSTPD exhibited a power conversion efficiency of 7.3% on the photovoltaic devices with an active area of 1 cm(2).

摘要

一种新的二噻吩并[3,2-b:2',3'-d]噻吩并[3,4-b]吡咯-4,6-二酮（PDTSTPD）与噻吩并吡咯-4,6-二酮（PDTSTPD）交替共聚的聚合物具有较低的光学带隙（1.73eV）和深的最高占据分子轨道能级（5.57eV）。研究发现，在二噻吩并噻吩单元中引入支化烷基链对于提高聚合物的溶解性至关重要。当与 PC(71)BM 共混时，PDTSTPD 在活性面积为 1cm(2)的光伏器件中表现出 7.3%的功率转换效率。

相似文献

1
Bulk heterojunction solar cells using thieno[3,4-c]pyrrole-4,6-dione and dithieno[3,2-b:2',3'-d]silole copolymer with a power conversion efficiency of 7.3%.使用噻吩并[3,4-c]吡咯-4,6-二酮和二噻吩并[3,2-b:2',3'-d]噻吩共聚物的体异质结太阳能电池，其功率转换效率为 7.3%。
J Am Chem Soc. 2011 Mar 30;133(12):4250-3. doi: 10.1021/ja200314m. Epub 2011 Mar 4.
2
A thieno[3,4-c]pyrrole-4,6-dione-based copolymer for efficient solar cells.基于噻吩并[3,4-c]吡咯-4,6-二酮的共聚物用于高效太阳能电池。
J Am Chem Soc. 2010 Apr 21;132(15):5330-1. doi: 10.1021/ja101888b.
3
Molecular design of photovoltaic materials for polymer solar cells: toward suitable electronic energy levels and broad absorption.用于聚合物太阳能电池的光伏材料的分子设计：实现合适的电子能级和宽吸收。
Acc Chem Res. 2012 May 15;45(5):723-33. doi: 10.1021/ar2002446. Epub 2012 Jan 30.
4
Alkyl chain engineering on a dithieno[3,2-b:2',3'-d]silole-alt-dithienylthiazolo[5,4-d]thiazole copolymer toward high performance bulk heterojunction solar cells.通过对二噻吩并[3,2-b:2',3'-d]硅噻吩--alt-二噻吩并[5,4-d]噻唑并[5,4-d]噻唑共聚物的烷基链工程化，制备高性能体异质结太阳能电池。
Chem Commun (Camb). 2011 Sep 7;47(33):9474-6. doi: 10.1039/c1cc13477a. Epub 2011 Jul 22.
5
Low-band-gap conjugated polymers of dithieno[2,3-b:7,6-b]carbazole and diketopyrrolopyrrole: effect of the alkyl side chain on photovoltaic properties.基于二噻吩并[2,3-b:7,6-b]咔唑和二酮吡咯并吡咯的低带隙共轭聚合物：烷基侧链对光伏性能的影响。
ACS Appl Mater Interfaces. 2013 Jun 26;5(12):5741-7. doi: 10.1021/am401175v. Epub 2013 Jun 10.
6
A new class of semiconducting polymers for bulk heterojunction solar cells with exceptionally high performance.一类新型半导体聚合物，用于具有极高性能的体异质结太阳能电池。
Acc Chem Res. 2010 Sep 21;43(9):1227-36. doi: 10.1021/ar1000296.
7
Bithiopheneimide-dithienosilole/dithienogermole copolymers for efficient solar cells: information from structure-property-device performance correlations and comparison to thieno[3,4-c]pyrrole-4,6-dione analogues.双噻吩并[3,2-b]噻吩并[2,3-b]噻吩并[3,2-b]噻吩并[2,3-d]噻吩并[3,4-c]吡咯-4,6-二酮类似物的高效太阳能电池：结构-性能-器件性能相关性的信息和比较。
J Am Chem Soc. 2012 Nov 7;134(44):18427-39. doi: 10.1021/ja3081583. Epub 2012 Oct 24.
8
An Alternating Copolymer Derived from Indolo[3,2-b]carbazole and 4,7-Di(thieno[3,2-b]thien-2-yl)-2,1,3-benzothiadiazole for Photovoltaic Cells.一种用于光伏电池的由吲哚并[3,2-b]咔唑和4,7-二(噻吩并[3,2-b]噻吩-2-基)-2,1,3-苯并噻二唑衍生的交替共聚物。
Macromol Rapid Commun. 2010 Jul 15;31(14):1287-92. doi: 10.1002/marc.201000062. Epub 2010 May 4.
9
Conjugated polymers based on benzo[2,1-b:3,4-b']dithiophene with low-lying highest occupied molecular orbital energy levels for organic photovoltaics.基于苯并[2,1-b:3,4-b']二噻吩的低 HOMO 能级共轭聚合物用于有机光伏。
ACS Appl Mater Interfaces. 2009 Jul;1(7):1613-21. doi: 10.1021/am900327n.
10
Development of novel conjugated donor polymers for high-efficiency bulk-heterojunction photovoltaic devices.用于高效体异质结光伏器件的新型共轭供体聚合物的开发。
Acc Chem Res. 2009 Nov 17;42(11):1709-18. doi: 10.1021/ar900061z.

引用本文的文献

1
Recent Advances in Graphene-Enabled Materials for Photovoltaic Applications: A Comprehensive Review.用于光伏应用的石墨烯基材料的最新进展：全面综述。
ACS Omega. 2024 Mar 9;9(11):12403-12425. doi: 10.1021/acsomega.3c07994. eCollection 2024 Mar 19.
2
Silicon nanocrystal hybrid photovoltaic devices for indoor light energy harvesting.用于室内光能采集的硅纳米晶混合光伏器件。
RSC Adv. 2020 Mar 27;10(21):12611-12618. doi: 10.1039/d0ra00804d. eCollection 2020 Mar 24.
3
Recent developments in the synthesis of regioregular thiophene-based conjugated polymers for electronic and optoelectronic applications using nickel and palladium-based catalytic systems.
使用镍基和钯基催化体系合成用于电子和光电子应用的区域规整噻吩基共轭聚合物的最新进展。
RSC Adv. 2020 Jan 27;10(8):4322-4396. doi: 10.1039/c9ra09712k. eCollection 2020 Jan 24.
4
Solution-processed two-dimensional materials for next-generation photovoltaics.用于下一代光伏的溶液处理二维材料。
Chem Soc Rev. 2021 Nov 1;50(21):11870-11965. doi: 10.1039/d1cs00106j.
5
From Red to Green Luminescence via Surface Functionalization. Effect of 2-(5-Mercaptothien-2-yl)-8-(thien-2-yl)-5-hexylthieno[3,4-]pyrrole-4,6-dione Ligands on the Photoluminescence of Alloyed Ag-In-Zn-S Nanocrystals.通过表面功能化实现从红色到绿色发光。2-(5-巯基噻吩-2-基)-8-(噻吩-2-基)-5-己基噻吩并[3,4-]吡咯-4,6-二酮配体对合金化Ag-In-Zn-S纳米晶体光致发光的影响。
Inorg Chem. 2020 Oct 5;59(19):14594-14604. doi: 10.1021/acs.inorgchem.0c02468. Epub 2020 Sep 17.
6
Tackling Performance Challenges in Organic Photovoltaics: An Overview about Compatibilizers.解决有机光伏性能挑战：关于相容剂的概述。
Molecules. 2020 May 8;25(9):2200. doi: 10.3390/molecules25092200.
7
Recent Development on Narrow Bandgap Conjugated Polymers for Polymer Solar Cells.用于聚合物太阳能电池的窄带隙共轭聚合物的最新进展
Polymers (Basel). 2017 Jan 28;9(2):39. doi: 10.3390/polym9020039.
8
Direct (Hetero)Arylation for the Synthesis of Molecular Materials: Coupling Thieno[3,4-c]pyrrole-4,6-dione with Perylene Diimide to Yield Novel Non-Fullerene Acceptors for Organic Solar Cells.直接（杂芳基）芳基化合成分子材料：噻吩并[3,4-c]吡咯-4,6-二酮与苝二酰亚胺的偶联，得到用于有机太阳能电池的新型非富勒烯受体。
Molecules. 2018 Apr 17;23(4):931. doi: 10.3390/molecules23040931.
9
Charge migration and charge transfer in molecular systems.分子系统中的电荷迁移与电荷转移。
Struct Dyn. 2017 Dec 27;4(6):061508. doi: 10.1063/1.4996505. eCollection 2017 Nov.
10
Knowledge Domain and Emerging Trends in Organic Photovoltaic Technology: A Scientometric Review Based on CiteSpace Analysis.有机光伏技术的知识领域与新兴趋势：基于CiteSpace分析的科学计量学综述
Front Chem. 2017 Sep 15;5:67. doi: 10.3389/fchem.2017.00067. eCollection 2017.