Jiang Jian-Shuang, Liu Zhao-Zhen, Feng Zi-Ming, Yang Ya-Nan, Zhang Pei-Cheng
Institute of Materia Medica, Chinese Academy of Medical Sciences and Peking Union Medical College (Key Laboratory of Bioactive Substances and Resources Utilization of Chinese Herbal Medicine, Ministry of Education), Beijing, China.
J Asian Nat Prod Res. 2011 Mar;13(3):276-80. doi: 10.1080/10286020.2011.551828.
A new nortriterpenoid saponin, 3β,17β-dihydroxy-28-nor-12-oleanen-16-one 3-O-β-d-galactopyranosyl (1 → 2)-{α-l-arabinopyranosyl (1 → 3)-[α-l-arabinofuranosyl (1 → 4)-β-d-glucuronopyranoside]} (1), along with two pairs of known isomers, was isolated from the roots of Symplocos caudata Wall. Their structures were elucidated by spectroscopic and chemical methods.
从尾叶山矾(Symplocos caudata Wall.)的根中分离得到一种新的三萜皂苷,3β,17β - 二羟基 - 28 - 降 - 12 - 齐墩果烯 - 16 - 酮3 - O - β - D - 吡喃半乳糖基(1→2)-{α - L - 吡喃阿拉伯糖基(1→3)-[α - L - 呋喃阿拉伯糖基(1→4)-β - D - 吡喃葡萄糖醛酸苷]}(1),以及两对已知异构体。通过光谱和化学方法阐明了它们的结构。