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樟科油桐(Cinnamomum camphora)中富含中链三酰甘油(MCT)的种子油的特性及其氧化稳定性。

Characterization of medium-chain triacylglycerol (MCT)-enriched seed oil from Cinnamomum camphora (Lauraceae) and its oxidative stability.

机构信息

State Key Laboratory of Food Science and Technology, Institute for Advanced Study, Nanchang University, Nanchang, Jiangxi, China.

出版信息

J Agric Food Chem. 2011 May 11;59(9):4771-8. doi: 10.1021/jf200188r. Epub 2011 Apr 13.

Abstract

Medium-chain triacylglycerol (MCT)-enriched oil was extracted by supercritical fluid extraction of carbon dioxide (SFE-CO(2)) from Cinnamomum camphora seeds. The SFE-CO(2) process was optimized using the Box-Behnken design (BBD). The maximum oil yield (42.82%) was obtained under the optimal SFE-CO(2) conditions: extraction pressure, 21.16 MPa; extraction temperature, 45.67 °C; and extraction time, 2.38 h. Subsequently, the physicochemical characteristics, fatty acid composition, triacylglycerol (TAG) composition, tocopherol content, and DSC profile as well as oxidative stabilities of C. camphora seed oil (CCSO) were studied. Results showed that CCSO contained two major medium-chain fatty acids, capric acid (53.27%) and lauric acid (39.93%). The predominant TAG species in CCSO was LaCC/CLaC (ECN 32, 79.29%). Meanwhile, it can be found that CCSO had much higher oxidative stabilities than coconut oil due to the higher content of tocopherols in CCSO (α-tocopherol, 8.67 ± 0.51 mg/100 g; γ-tocopherol, 22.6 ± 1.02 mg/100 g; δ-tocopherol, 8.38 ± 0.47 mg/100 g). Conclusively, CCSO with such a high level of MCTs and high oxidative stabilities could be potentially applied in special food for specific persons such as weak patients and overweight persons because oils enriched in MCTs can be rapidly absorbed into body to provide energy without fat accumulation.

摘要

从中性脂肪油(MCT)中提取富含油通过超临界二氧化碳(SFE-CO(2))从樟科种子。使用 Box-Behnken 设计(BBD)优化 SFE-CO(2)工艺。在最佳 SFE-CO(2)条件下获得最大油产量(42.82%):萃取压力,21.16 MPa; 萃取温度,45.67°C; 和萃取时间,2.38 h。随后,研究了樟科种子油(CCSO)的理化特性、脂肪酸组成、三酰基甘油(TAG)组成、生育酚含量和 DSC 图谱以及氧化稳定性。结果表明,CCSO 含有两种主要的中链脂肪酸,癸酸(53.27%)和月桂酸(39.93%)。CCSO 中主要的 TAG 种类为 LaCC/CLaC(ECN 32,79.29%)。同时,由于 CCSO 中生育酚含量较高(α-生育酚,8.67±0.51 mg/100 g;γ-生育酚,22.6±1.02 mg/100 g;δ-生育酚,8.38±0.47 mg/100 g),可以发现 CCSO 的氧化稳定性比椰子油高得多。总之,CCSO 具有如此高的 MCT 水平和高氧化稳定性,由于富含 MCT 的油可以迅速被人体吸收提供能量而不会积累脂肪,因此可能适用于特定人群的特殊食品,如体弱患者和超重人群。

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