Bouffard Jean, Itami Kenichiro
Department of Chemistry, Graduate School of Science, Nagoya University, Chikusa, Nagoya 464-8602, Japan.
Top Curr Chem. 2010;292:231-80. doi: 10.1007/128_2009_12.
A review is presented of synthetic methods for the preparation of biaryls by the rhodium-catalyzed C-H bond arylation of arenes with aryl halides (C-H/ C-X couplings), arylmetal reagents (C-H/C-M couplings) and arenes (C-H/C-H couplings), with an emphasis on postulated mechanisms and their implications on reactivity, selectivity and substrate scope.
本文综述了通过铑催化芳烃与芳基卤化物的C-H键芳基化反应（C-H/C-X偶联）、芳基金属试剂（C-H/C-M偶联）和芳烃（C-H/C-H偶联）制备联芳基的合成方法，重点介绍了推测的反应机理及其对反应活性、选择性和底物范围的影响。
