二碘代{2-(吗啉-4-基)-N-[1-(2-吡啶基)亚乙基]乙胺-κN,N',N''}锌
Diiodido{2-(morpholin-4-yl)-N-[1-(2-pyrid-yl)ethyl-idene]ethanamine-κN,N',N''}zinc.
作者信息
Suleiman Gwaram Nura, Khaledi Hamid, Mohd Ali Hapipah
机构信息
Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2011 May 1;67(Pt 5):m628. doi: 10.1107/S1600536811014656. Epub 2011 Apr 22.
In the title compound, [ZnI(2)(C(13)H(19)N(3)O)], the Zn(II) ion is five-coordinated in a distorted square-pyramidal geometry, in which the basal plane is defined by three N atoms from the Schiff base ligand and one iodide ion. A second iodide ligand, situated in the apical position, completes the coordination geometry. In the crystal structure, C-H⋯O hydrogen bonds link a pair of mol-ecules around an inversion centre into a dimer.
在标题化合物[ZnI₂(C₁₃H₁₉N₃O)]中，Zn(II)离子以扭曲的四方锥几何构型进行五配位，其中基面由席夫碱配体的三个N原子和一个碘离子定义。位于顶端位置的第二个碘配体完成了配位几何构型。在晶体结构中，C—H⋯O氢键将一对分子围绕一个反演中心连接成二聚体。
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