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中国渤海湾表层沉积物中有机氯农药(OCPs)的分布。

The distribution of organochlorine pesticides (OCPs) in surface sediments of Bohai Sea Bay, China.

机构信息

Environmental Information Institute, Dalian Maritime University, Dalian, 116026, China.

出版信息

Environ Monit Assess. 2012 Apr;184(4):1921-7. doi: 10.1007/s10661-011-2089-4. Epub 2011 May 11.

Abstract

The residues of organochlorine pesticides (OCPs) in 19 surface sediments of Bohai Sea Bay were determined in this study. Total OCP concentration in surface sediment ranged from 9.01 to 18.04 ng/g dry weight, with a mean concentration of 12.50 ng/g. These findings are in the mid-range of pesticide concentrations compared to those reported in other regions worldwide. DDTs and HCHs were the predominant species. The α-HCH/β-HCH ratios and the predominant γ-HCH indicate that the technical HCH contamination was due mainly to historical usage, although there appeared to be a fresh input of lindane. The results from (DDD + DDE)/ΣDDTs and DDD/DDE calculations suggest that the usage of DDT in agricultural activities was not terminated, and the historical/fresh inputs of DDT in these areas could be more easily degraded into DDD under an anoxic condition. PCA implies that the recent usage of DDT could serve as important fresh input sources for OCPs.

摘要

本研究测定了渤海湾 19 个表层沉积物中有机氯农药(OCPs)的残留量。表层沉积物中总 OCP 浓度范围为 9.01-18.04ng/g 干重,平均值为 12.50ng/g。与世界其他地区报道的浓度相比,这些发现处于农药浓度的中等范围。滴滴涕(DDTs)和六氯环己烷(HCHs)是主要的种类。α-HCH/β-HCH 比值和主要的γ-HCH 表明,技术 HCH 的污染主要是由于历史上的使用,尽管似乎有林丹的新输入。(DDD+DDE)/ΣDDTs 和 DDD/DDE 计算的结果表明,农业活动中滴滴涕的使用尚未终止,在这些地区,DDT 的历史/新鲜输入在缺氧条件下更容易降解为 DDD。PCA 表明,滴滴涕的近期使用可能是 OCPs 的重要新鲜输入源。

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