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[2,6-双（对甲苯基亚氨基甲基）吡啶-κN,N',N'']二氯化铜（II）

[2,6-Bis(p-tol-ylimino-meth-yl)pyridine-κN,N',N'']dichloridocopper(II).

作者信息

Li Xiao-Ping, Zhao Jian-She, Ng Seik Weng

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 25;66(Pt 10):m1297. doi: 10.1107/S1600536810037025.

DOI:10.1107/S1600536810037025
PMID:21587436
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2983193/
Abstract

The title compound, [CuCl(2)(C(21)H(19)N(3))], lies on a twofold rotation axis that passes through the N(pyrid-yl)-Cu bond; this symmetry element relates one half of the organic ligand to the other as well as one Cl ligand to the other. The three N atoms span the axial-equatorial-axial sites of the trigonal-bipyramidal coordination polyhedron; the geometry of the Cu(II) atom is 31% distorted from trigonal-bipyramidal (towards square-pyramidal along the Berry pseudorotation pathway).

摘要

标题化合物[CuCl₂(C₂₁H₁₉N₃)]位于一个通过N(吡啶基)-Cu键的二重旋转轴上；该对称元素将有机配体的一半与另一半以及一个Cl配体与另一个Cl配体联系起来。三个N原子占据三角双锥配位多面体的轴向-赤道-轴向位置；Cu(II)原子的几何形状相对于三角双锥有31%的畸变（沿着贝里假旋转途径向四方锥畸变）。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e3d3/2983193/8626a8414c7c/e-66-m1297-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e3d3/2983193/8626a8414c7c/e-66-m1297-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e3d3/2983193/8626a8414c7c/e-66-m1297-fig1.jpg

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