（格式-κO，O'）双-（1,10-菲咯啉-κN，N'）高氯酸锰（II）
(Formato-κO,O')bis-(1,10-phenanthroline-κN,N')manganese(II) perchlorate.
作者信息
Zhao Jun, Zheng Xue-Gang, Hu Zong-Zhi
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Nov 21;65(Pt 12):m1642. doi: 10.1107/S1600536809049277.
Abstract
In the title complex, [Mn(CHO(2))(C(12)H(8)N(2))(2)]ClO(4), the Mn(II) cation is chelated by two 1,10-phenanthroline (phen) ligands and one formate anion in a distorted MnN(4)O(2) octa-hedral geometry. The two phen planes are oriented at a dihedral angle of 57.48 (11)°. The perchlorate anion links with the Mn complex cation via weak C-H⋯O hydrogen bonding.
摘要
在标题配合物[Mn(CHO₂)(C₁₂H₈N₂)₂]ClO₄中，Mn(II)阳离子由两个1,10 - 菲咯啉（phen）配体和一个甲酸根阴离子以扭曲的MnN₄O₂八面体几何构型螯合。两个phen平面以57.48 (11)°的二面角取向。高氯酸根阴离子通过弱的C—H⋯O氢键与Mn配合物阳离子相连。
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