Chen Shui-Sheng, Yang Sen-Lin, Zhang Shu-Ping, Lu Zi-Qiang
Acta Crystallogr Sect E Struct Rep Online. 2010 Nov 6;66(Pt 12):m1501-2. doi: 10.1107/S1600536810044053.
In the title compound, Mn(CHO(2))(2)(C(12)H(10)N(4))(2), the Mn(II) atom and the benzene ring of the ligand lie on an inversion centers. The Mn(II) atom has an octa-hedral coordination environment composed of four N atoms from two different symmetry-related N-heterocyclic ligands forming the basal plane, and two O atoms from symmetry-related formate anions occupying the apical positions. The title compound forms a two-dimensional (4,4) net parallel to (100) with all the Mn(II) atoms lying on a plane. The crystal structure is consolidated by inter-molecular N-H⋯O hydrogen bonds..
在标题化合物[Mn(CHO₂)₂(C₁₂H₁₀N₄)₂]ₙ中,Mn(II)原子和配体的苯环位于对称中心上。Mn(II)原子具有八面体配位环境,由来自两个不同对称相关的N-杂环配体的四个N原子形成基面,以及来自对称相关甲酸根阴离子的两个O原子占据顶点位置。标题化合物形成了一个平行于(100)的二维(4,4)网络,所有Mn(II)原子都位于一个平面上。晶体结构通过分子间N-H⋯O氢键得以巩固。