Zhu Lei, Wang Dabin, Xu Hongyan
Acta Crystallogr Sect E Struct Rep Online. 2010 Apr 10;66(Pt 5):m513. doi: 10.1107/S1600536810012638.
In the title compound, [Mn(C(10)H(7)N(2)O(2))(2)(H(2)O)(4)], the Mn(II) atom, lying on an inversion center, has an octa-hedral environment with four coordinated water mol-ecules in the equatorial plane and two N atoms from two 4-(imidazol-1-yl)benzoate ligands at the axial sites. The complex mol-ecules are connected into a three-dimensional network by extensive hydrogen bonds between the water mol-ecules and the carboxyl-ate O atoms.
在标题化合物[Mn(C₁₀H₇N₂O₂)₂(H₂O)₄]中,位于对称中心的Mn(II)原子具有八面体环境,赤道平面上有四个配位水分子,轴向位置有来自两个4-(咪唑-1-基)苯甲酸酯配体的两个N原子。通过水分子与羧酸根O原子之间广泛的氢键,配合物分子连接成三维网络。