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二水合-1κO,2κO-(2,2'-联-1H-咪唑-1κN,N)(草酸根-2κO,O)二-μ-氧化-κO:O-二氧化-1κO,2κO-二钼(V)三水合物

Diaqua-1κO,2κO-(2,2'-bi-1H-imidazole-1κN,N)(oxalato-2κO,O)di-μ-oxido-κO:O-dioxido-1κO,2κO-dimolyb-denum(V) trihydrate.

作者信息

Zhang Xiutang, Wei Peihai, Shi Congwen, Li Bin, Hu Bo

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Dec 9;66(Pt 1):m26-7. doi: 10.1107/S1600536809052003.

DOI:10.1107/S1600536809052003
PMID:21579926
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2980048/
Abstract

In the title compound, [Mo(2)(C(2)O(4))O(4)(C(6)H(6)N(4))(H(2)O)(2)]·3H(2)O, the coordination polyhedra for both Mo(V) atoms consist of two bridging O atoms, two atoms of the chelating ligand (oxalate or diimidazole), a terminal O atom and one H(2)O mol-ecule. The two distorted octa-hedrally coordinated Mo(V) atoms are linked together via O-O edge-sharing and Mo-Mo inter-actions with a Mo-Mo bond length of 2.564 (5) Å. Uncoordinated water mol-ecules are situated in the voids of the crystal structure. N-H⋯O and O-H⋯O hydrogen bonding between the neutral mol-ecules and the water mol-ecules lead to a consolidation of the structure.

摘要

在标题化合物[Mo₂(C₂O₄)O₄(C₆H₆N₄)(H₂O)₂]·3H₂O中，两个Mo(V)原子的配位多面体均由两个桥连O原子、螯合配体（草酸根或二咪唑）的两个原子、一个端基O原子和一个H₂O分子组成。两个扭曲的八面体配位的Mo(V)原子通过O - O边共享和Mo - Mo相互作用连接在一起，Mo - Mo键长为2.564(5) Å。未配位的水分子位于晶体结构的空隙中。中性分子与水分子之间的N - H⋯O和O - H⋯O氢键导致结构的巩固。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e65a/2980048/0d373c725449/e-66-00m26-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e65a/2980048/36c40761de42/e-66-00m26-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e65a/2980048/0d373c725449/e-66-00m26-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e65a/2980048/36c40761de42/e-66-00m26-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e65a/2980048/0d373c725449/e-66-00m26-fig2.jpg

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