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catena-Poly[[[tetra-aqua-cobalt(II)]-μ-4,4'-bipyridine-κN:N'] bis-(perchlorate) 4,4'-bipyridine disolvate dihydrate].链状聚[[[四水合钴（II）]-μ-4,4'-联吡啶-κN:N']双（高氯酸盐）4,4'-联吡啶二溶剂合物二水合物]
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catena-Poly[[[tetra-aqua-cobalt(II)]-μ-4,4'-bipyridine-κN:N'] 2-[4-(2-carboxyl-ato-eth-yl)phen-oxy]acetate].链状聚[[[四水合钴（II）]-μ-4,4'-联吡啶-κN:N'] 2-[4-（2-羧基-乙基）苯氧基]乙酸酯]
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catena-Poly[[[tetra-aqua-cobalt(II)]-μ-4,4'-bipyridine-κN:N'] pyridine-3,5-dicarboxyl-ate trihydrate].链状聚[[[四水合钴（II）]-μ-4,4'-联吡啶-κN:N']吡啶-3,5-二羧酸盐三水合物]
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cis-Aqua-bis(2,2'-bipyridine-κN,N')fluoridochromium(III) bis-(perchlorate) dihydrate.顺式-水-双（2,2'-联吡啶-κN,N'）氟铬（III）双（高氯酸盐）二水合物
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catena-Poly[[[(dimethyl-malonato-κO:O')(perchlorato-κO)copper(II)]-μ-bis-(3-pyridylmeth-yl)piperazinediium-κN:N] perchlorate dihydrate].链状聚[[[(二甲基丙二酸根-κO:O')(高氯酸根-κO)铜(II)]-μ-双-(3-吡啶甲基)哌嗪二铵-κN:N]高氯酸盐二水合物]
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catena-Poly[[[tetra-aqua-manganese(II)]-μ-4,4'-bipyridine] bis-(3-hydroxy-cinnamate) dihydrate].链状聚[[[四水合锰（II）]-μ-4,4'-联吡啶]双（3-羟基肉桂酸酯）二水合物]
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本文引用的文献

1
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.

链状聚[[[四水合钴（II）]-μ-4,4'-联吡啶-κN:N']双（高氯酸盐）4,4'-联吡啶二溶剂合物二水合物]

catena-Poly[[[tetra-aqua-cobalt(II)]-μ-4,4'-bipyridine-κN:N'] bis-(perchlorate) 4,4'-bipyridine disolvate dihydrate].

作者信息

Nettleman Joseph H, Laduca Robert L

机构信息

Lyman Briggs College, Department of Chemistry, Michigan State University, East Lansing, MI 48825, USA.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Oct 31;64(Pt 11):m1485. doi: 10.1107/S1600536808035125.

DOI:10.1107/S1600536808035125
PMID:21580916
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2959782/
Abstract

In the title compound, {Co(C(10)H(8)N(2))(H(2)O)(4)(2)·2C(10)H(8)N(2)·2H(2)O}(n), slightly distorted octa-hedrally coordinated Co(II) ions situated on inversion centers are linked into polycationic chains through 4,4'-bipyridine tethering ligands. These are connected into supra-molecular layers by hydrogen bonding involving aqua ligands, perchlorate anions and uncoordinated water mol-ecules. A twofold inter-penetrated primitive cubic supra-molecular network is formed by the inter-action of pseudo-layers by hydrogen bonding between aqua ligands and unligated 4,4'-bipyridine mol-ecules.

摘要

在标题化合物{Co(C₁₀H₈N₂)(H₂O)₄₂·2C₁₀H₈N₂·2H₂O}ₙ中，位于对称中心的Co(II)离子呈略微扭曲的八面体配位，通过4,4'-联吡啶连接配体连接成聚阳离子链。这些通过涉及水合配体、高氯酸根阴离子和未配位水分子的氢键连接成超分子层。通过水合配体与未配位的4,4'-联吡啶分子之间的氢键作用，伪层相互作用形成了一个具有双重互穿的原始立方超分子网络。