一水合{双(3,5 - 二甲基 - 吡唑 - 1 - 基)甲烷}{N - [1 - (2 - 氧化苯基)亚乙基]-dl - 丙氨酸根}铜(II)
[Bis(3,5-dimethyl-pyrazol-1-yl)methane]{N-[1-(2-oxidophen-yl)ethyl-idene]-dl-alaninato}copper(II) monohydrate.
作者信息
Zhao Gan-Qing, Xue Ling-Wei, Hao Cheng-Jun, Chen Li-Hua, Wu Hua-Tao
机构信息
School of Chemistry and Chemical Engineering, Pingdingshan University, Pingdingshan 467000, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 Nov 13;64(Pt 12):m1553. doi: 10.1107/S1600536808037264.
In the title compound, [Cu(C(11)H(11)NO(3))(C(11)H(16)N(4))]·H(2)O, the Cu(II) atom is five-coordinate in a distorted square-pyramidal geometry. The basal positions are occupied by three donor atoms from the tridentate Schiff base ligand and by one N atom from a bis-(3,5-dimethyl-prazol-l-yl)methane ligand. The apical position is occupied by the N atom of the other ligand of this type. There are only van der Waals contacts in the crystal structure.
在标题化合物[Cu(C₁₁H₁₁NO₃)(C₁₁H₁₆N₄)]·H₂O中，Cu(II)原子呈扭曲的四方锥几何构型，为五配位。其基面位置由三齿席夫碱配体的三个供体原子和双(3,5-二甲基-吡唑-1-基)甲烷配体的一个N原子占据。顶端位置由这种类型的另一个配体的N原子占据。晶体结构中仅存在范德华接触。
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