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[(2-Morpholinoeth-yl)(2-pyridylmethyl-ene)amine]dithio-cyanato-zinc(II).

作者信息

Cai Bang-Hong

机构信息

Department of Chemistry, Jiaying University, Meizhou Guangdong 514015, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Jan 8;65(Pt 2):m142. doi: 10.1107/S1600536808044061.

Abstract

The title compound, [Zn(NCS)(2)(C(12)H(17)N(3)O)], was prepared by the reaction of zinc acetate with pyridine-2-carbaldehyde, 2-morpholinoethyl-amine and ammonium thio-cyanate in an ethanol solution. The Zn(II) atom is five coordinate with a distorted trigonal-bipyramidal geometry, coordinating with three N atoms of the Schiff base (2-morpholinoeth-yl)(2-pyridylmethyl-idene)amine and two N atoms from two thio-cyanate ligands. The morpholine ring adopts a chair configuration.

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3e5d/2968346/868fc4e9bfb6/e-65-0m142-fig1.jpg

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