三氯[3-二甲基氨基-1-(2-吡啶基)丙-2-烯-1-酮-κN]水合锰(II)氯化物
Triaqua-chlorido[3-dimethyl-amino-1-(2-pyrid-yl)prop-2-en-1-one-κN]manganese(II) chloride.
作者信息
Chu Zhao-Lian
机构信息
School of Chemistry and Chemical Engineering, Anhui University of Technology, Maanshan 243002, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 1;65(Pt 8):m855. doi: 10.1107/S1600536809024192.
In the title compound, [MnCl(C(10)H(12)N(2)O)(H(2)O)(3)]Cl, the Mn(II) ion has a distorted octa-hedral coordination environment formed by one N and one O atom from the chelating 3-dimethyl-amino-1-(2-pyrid-yl)prop-2-en-1-one ligand, one chloride anion and three coordinated water mol-ecules. Inter-molecular O-H⋯O and O-H⋯Cl hydrogen bonds link the cations and anions into layers parallel to the ac plane.
在标题化合物[MnCl(C₁₀H₁₂N₂O)(H₂O)₃]Cl中，Mn(II)离子具有一个扭曲的八面体配位环境，该环境由来自螯合的3-二甲基氨基-1-(2-吡啶基)丙-2-烯-1-酮配体的一个N原子和一个O原子、一个氯离子阴离子以及三个配位水分子形成。分子间的O—H⋯O和O—H⋯Cl氢键将阳离子和阴离子连接成平行于ac平面的层。
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