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高氯酸{(+)-(1R,2R)-1,2-二苯基-2,2'-[乙烷-1,2-二基双(腈基亚甲基)]-二苯酚根}二吡啶合钴(III)倍半水合物

{(+)-(1R,2R)-1,2-Diphenyl-2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]-di-phenol-ato}dipyridine-cobalt(III) perchlorate sesquihydrate.

作者信息

Zhou Lian-Wen

机构信息

Department of Chemistry, Dezhou University, Dezhou 253023, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Jan 23;65(Pt 2):m226. doi: 10.1107/S1600536809002293.

DOI:10.1107/S1600536809002293
PMID:21581817
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2968403/
Abstract

In title complex, [Co(C(28)H(22)N(2)O(2))(C(5)H(5)N)(2)]ClO(4)·1.5H(2)O, the Co(III) ion is in a slightly distorted octa-hedral coordination environment with the pyridine ligands in a trans arrangement. In addition to the cation and anion, the asymmetric unit also contains three half-occupancy solvent water mol-ecules and all components are connected via inter-molecular O-H⋯O hydrogen bonds.

摘要

在标题配合物[Co(C₂₈H₂₂N₂O₂)(C₅H₅N)₂]ClO₄·1.5H₂O中，Co(III)离子处于略微扭曲的八面体配位环境中，吡啶配体呈反式排列。除阳离子和阴离子外，不对称单元还包含三个半占据的溶剂水分子，所有组分通过分子间O—H⋯O氢键相连。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5b16/2968403/217e1a4ca567/e-65-0m226-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5b16/2968403/217e1a4ca567/e-65-0m226-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5b16/2968403/217e1a4ca567/e-65-0m226-fig1.jpg

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