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高氯酸双（4-氯吡啶）{2,2'-[乙烷-1,2-二基双（腈基亚甲基）]二酚根合}钴（III）甲醇单溶剂合物

Bis(4-chloro-pyridine){2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato}cobalt(III) perchlorate methanol monosolvate.

作者信息

Zhang Daopeng

机构信息

College of Chemical Engineering, Shandong University of Technology, Zibo 255049, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Nov 24;66(Pt 12):m1633. doi: 10.1107/S1600536810047793.

DOI:10.1107/S1600536810047793
PMID:21589306
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3011786/
Abstract

In the title complex, [Co(C(16)H(14)N(2)O(2))(C(5)H(4)ClN)(2)]ClO(4)·CH(3)OH, the Co(III) ion is in a slightly distorted octa-hedral CoN(4)O(2) coordination environment with the two 4-chloro-pyridine ligands in a trans arrangement.

摘要

在标题配合物[Co(C₁₆H₁₄N₂O₂)(C₅H₄ClN)₂]ClO₄·CH₃OH中，Co(III)离子处于略微扭曲的八面体CoN₄O₂配位环境中，两个4-氯吡啶配体呈反式排列。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9a99/3011786/a162dce7042c/e-66-m1633-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9a99/3011786/a162dce7042c/e-66-m1633-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9a99/3011786/a162dce7042c/e-66-m1633-fig1.jpg

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