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Tetra-chlorido(1,10-phenanthroline-κN,N')platinum(IV) monohydrate.

作者信息

Kim Nam-Ho, Hwang In-Chul, Ha Kwang

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Jan 28;65(Pt 2):m230. doi: 10.1107/S1600536809002694.

DOI:10.1107/S1600536809002694
PMID:21581820
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2968294/
Abstract

In the title complex, [PtCl(4)(C(12)H(8)N(2))]·H(2)O, the Pt(4+) ion is six-coordinated in a distorted octa-hedral environment by two N atoms of a 1,10-phenanthroline ligand and by four Cl atoms. As a result of the different trans effects of the N and Cl atoms, the Pt-Cl bonds trans to the N atom are slightly shorter than those trans to the Cl atom. The compound displays inter-molecular π-π inter-actions between the six-membered rings, with a centroid-centroid distance of 3.834 Å. There are also weak intra-molecular C-H⋯Cl hydrogen bonds. According to the IR spectrum, solvent water was present in the crystal, but owing to the high thermal motion of the uncoordinated O atom, the H atoms could not be detected.

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c971/2968294/e665c60fc159/e-65-0m230-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c971/2968294/8bcb960d5864/e-65-0m230-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c971/2968294/e665c60fc159/e-65-0m230-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c971/2968294/8bcb960d5864/e-65-0m230-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c971/2968294/e665c60fc159/e-65-0m230-fig2.jpg

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本文引用的文献

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A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
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Steric Crowding and Redox Reactivity in Platinum(II) and Platinum(IV) Complexes Containing Substituted 1,10-Phenanthrolines.含取代1,10-菲咯啉的铂（II）和铂（IV）配合物中的空间拥挤和氧化还原反应活性
Inorg Chem. 1996 May 22;35(11):3173-3182. doi: 10.1021/ic960125y.