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二氯双（2,2'-联吡啶-κN,N'）铂（IV）二氯化物一水合物

Bis(2,2'-bipyridine-κN,N')dichlorido-platinum(IV) dichloride monohydrate.

作者信息

Kim Nam-Ho, Hwang In-Chul, Ha Kwang

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Jan 14;65(Pt 2):m180. doi: 10.1107/S1600536809000725.

DOI:10.1107/S1600536809000725
PMID:21581784
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2968269/
Abstract

In the title complex, [PtCl(2)(C(10)H(8)N(2))(2)]Cl(2)·H(2)O, the Pt(4+) ion is six-coordinated in a distorted octa-hedral environment by four N atoms from the two 2,2'-bipyridine ligands and two Cl atoms. As a result of the different trans influences of the N and Cl atoms, the Pt-N bonds trans to the Cl atom are slightly longer than those trans to the N atom. The compound displays inter-molecular hydrogen bonding between the water mol-ecule and the Cl anions. There are inter-molecular π-π inter-actions between adjacent pyridine rings, with a centroid-centroid distance of 3.962 Å.

摘要

在标题配合物[PtCl₂(C₁₀H₈N₂)₂]Cl₂·H₂O中，Pt(IV)离子在扭曲的八面体环境中通过来自两个2,2'-联吡啶配体的四个N原子和两个Cl原子进行六配位。由于N和Cl原子的反位影响不同，与Cl原子反位的Pt-N键比与N原子反位的Pt-N键略长。该化合物在水分子和Cl⁻阴离子之间表现出分子间氢键。相邻吡啶环之间存在分子间π-π相互作用，质心-质心距离为3.962 Å。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b4fe/2968269/776ac2e29367/e-65-0m180-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b4fe/2968269/776ac2e29367/e-65-0m180-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b4fe/2968269/776ac2e29367/e-65-0m180-fig1.jpg

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