链状聚[[二水合钴（II）]-双（μ-3-羧基金刚烷-1-羧酸根-κO:O）]
catena-Poly[[diaquacobalt(II)]-bis(μ-3-carboxy-adamantane-1-carboxyl-ato-κO:O)].
作者信息
Tang Li-Ming, Xu Jia-Hui, Han Xiao-Yan, Xu Wei
机构信息
State Key Laboratory Base of Novel Functional Materials and Preparation Science, Faculty of Materials Science and Chemical Engineering, Institute of Solid Materials Chemistry, Ningbo University, Ningbo, Zhejiang, 315211, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 6;65(Pt 4):m375. doi: 10.1107/S1600536809007387.
In the title compound, Co(C(12)H(15)O(4))(2)(H(2)O)(2), adjacent Co(II) atoms ( symmetry) are bridged by 3-carboxy-adamantane-1-carboxyl-ate anions, forming a chain running along [001]. Inter-chain O-H⋯O hydrogen bonds link the chains into layers parallel to (100); the layers are further connected via inter-layer hydrogen bonds inter-actions, forming a three-dimensional framework.
在标题化合物[Co(C₁₂H₁₅O₄)₂(H₂O)₂]ₙ中，相邻的Co(II)原子（对称）由3-羧基金刚烷-1-羧酸根阴离子桥连，形成沿[001]方向延伸的链。链间的O—H⋯O氢键将这些链连接成平行于(100)的层；这些层通过层间氢键相互作用进一步连接，形成三维骨架。
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