溴化[三(3,5-二苯基-吡唑基)氢硼根合]镍(II)
[Tris(3,5-diphenyl-pyrazol-yl)hydro-borato]nickel(II) bromide.
作者信息
Harding David J, Harding Phimphaka, Adams Harry
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 13;65(Pt 7):m773. doi: 10.1107/S1600536809021606.
Abstract
In the title tris-(pyrazol-yl)borate (Tp(Ph2)) complex, [NiBr(C(45)H(34)BN(6))], the Ni, Br and B atoms lie on a crystallographic threefold axis and a distorted NiN(3)Br tetra-hedral geometry arises for the metal ion. In the crystal, C-H⋯(C=C) and C-H⋯π inter-actions help to establish the polar crystal packing.
摘要
在标题为三（吡唑基）硼酸酯（Tp(Ph2)）配合物[NiBr(C45H34BN6)]中，镍、溴和硼原子位于一个晶体学三重轴上，金属离子呈现出扭曲的NiN(3)Br四面体几何构型。在晶体中，C-H⋯(C=C)和C-H⋯π相互作用有助于建立极性晶体堆积。
Zotero 插件