二氯[三（1H-苯并咪唑-2-基甲基）胺-κN，N，N，N]铁（III）氯化物四氢呋喃单溶剂合物一水合物
Dichlorido[tris-(1H-benzimidazol-2-ylmeth-yl)amine-κN,N,N,N]iron(III) chloride tetra-hydro-furan monosolvate monohydrate.
作者信息
Wang Dong'e
机构信息
Department of Chemistry, Kashgar Teachers College, Kashgar 844000, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 27;65(Pt 7):m828. doi: 10.1107/S1600536809023423.
In the title compound, [FeCl(2)(C(24)H(21)N(7))]Cl·C(4)H(8)O·H(2)O, the Fe(III) atom is coordinated by four N atoms of the polybenzimidazole ligand and two Cl atoms in a distorted octa-hedral environment. The cation, anion, the uncoordinated water mol-ecule and the THF solvent molecule are linked by hydrogen bonds into a three-dimensional network structure. The THF molecule is disordered with two sets of sites in a 0.58 (1):0.42 (2) ratio..
在标题化合物[FeCl₂(C₂₄H₂₁N₇)]Cl·C₄H₈O·H₂O中，Fe(III)原子在扭曲的八面体环境中由多苯并咪唑配体的四个N原子和两个Cl原子配位。阳离子、阴离子、未配位的水分子和四氢呋喃溶剂分子通过氢键连接成三维网络结构。四氢呋喃分子以0.58 (1):0.42 (2)的比例在两组位置上无序排列。
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