Becker Eva, Kirchner Karl, Mereiter Kurt
Acta Crystallogr Sect E Struct Rep Online. 2009 May 14;65(Pt 6):m631. doi: 10.1107/S1600536809016894.
The title compound, [Ru(η(5)-C(5)H(5)){η(6)-C(6)H(2)(CH(3))(3)NH(2)}]PF(6), contains a sandwich complex with a mesitylamine unit which is significantly non-planar at the ipso-carbon of the amino group due to repulsive electronic effects with Ru. The ipso-carbon deviates by 0.107 (3) Å from the least-squares plane of the remaining five benzene ring atoms, which show an r.m.s. deviation of 0.005 Å. N-H⋯F hydrogen-bonding interactions help to consolidate the crystal packing.
标题化合物[Ru(η⁵-C₅H₅){η⁶-C₆H₂(CH₃)₃NH₂}]PF₆包含一个带有均三甲苯胺单元的夹心配合物，由于与钌之间的电子排斥作用，氨基的本位碳显著非平面。本位碳偏离其余五个苯环原子的最小二乘平面0.107 (3) Å，其余五个苯环原子的均方根偏差为0.005 Å。N-H⋯F氢键相互作用有助于巩固晶体堆积。
