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二氯{2-[2-(二甲基铵基)乙基-亚氨基甲基]-6-甲氧基苯酚根合}锌(II)

Dichlorido{2-[2-(dimethyl-ammonio)ethyl-imino-meth-yl]-6-methoxy-phenolato}zinc(II).

作者信息

Datta Amitabha, Chuang Nien-Tsu, Huang Jui-Hsien, Lee Hon Man

机构信息

National Changhua University of Education, Department of Chemistry, Changhua, Taiwan 50058.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 22;65(Pt 8):m964. doi: 10.1107/S1600536809028220.

DOI:10.1107/S1600536809028220
PMID:21583409
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2977086/
Abstract

The structure of the title complex, [ZnCl(2)(C(12)H(18)N(2)O(2))], contains a zwitterionic Schiff base ligand. The complex adopts a distorted tetra-hedral coordination geometry around the metal centre with the Schiff base ligand coordinated in a bidentate fashion via the imine N and phenolate O atoms. In the crystal, inter-molecular N-H⋯O and C-H⋯Cl hydrogen bonds link the mol-ecules into chains parallel to the c-glide planes.

摘要

标题配合物[ZnCl₂(C₁₂H₁₈N₂O₂)]的结构包含一个两性离子席夫碱配体。该配合物在金属中心周围采用扭曲的四面体配位几何构型，席夫碱配体通过亚胺氮原子和酚氧原子以双齿方式配位。在晶体中，分子间的N-H⋯O和C-H⋯Cl氢键将分子连接成平行于c滑移面的链。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a0e1/2977086/0fd9d5b3e258/e-65-0m964-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a0e1/2977086/8e2c042a6195/e-65-0m964-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a0e1/2977086/0fd9d5b3e258/e-65-0m964-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a0e1/2977086/8e2c042a6195/e-65-0m964-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a0e1/2977086/0fd9d5b3e258/e-65-0m964-fig2.jpg

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