二氯{2-[2-(二甲基铵基)乙基-亚氨基甲基]-6-甲氧基苯酚根合}锌(II)
Dichlorido{2-[2-(dimethyl-ammonio)ethyl-imino-meth-yl]-6-methoxy-phenolato}zinc(II).
作者信息
Datta Amitabha, Chuang Nien-Tsu, Huang Jui-Hsien, Lee Hon Man
机构信息
National Changhua University of Education, Department of Chemistry, Changhua, Taiwan 50058.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 22;65(Pt 8):m964. doi: 10.1107/S1600536809028220.
The structure of the title complex, [ZnCl(2)(C(12)H(18)N(2)O(2))], contains a zwitterionic Schiff base ligand. The complex adopts a distorted tetra-hedral coordination geometry around the metal centre with the Schiff base ligand coordinated in a bidentate fashion via the imine N and phenolate O atoms. In the crystal, inter-molecular N-H⋯O and C-H⋯Cl hydrogen bonds link the mol-ecules into chains parallel to the c-glide planes.
标题配合物[ZnCl₂(C₁₂H₁₈N₂O₂)]的结构包含一个两性离子席夫碱配体。该配合物在金属中心周围采用扭曲的四面体配位几何构型，席夫碱配体通过亚胺氮原子和酚氧原子以双齿方式配位。在晶体中，分子间的N-H⋯O和C-H⋯Cl氢键将分子连接成平行于c滑移面的链。
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