二氯{2-[(2-异丙基铵基乙基)亚氨基甲基]-5-甲氧基苯酚根合}锌(II)
Dichlorido{2-[(2-isopropyl-ammonio-ethyl)imino-meth-yl]-5-methoxy-phenolato}zinc(II).
作者信息
Han Zhen-Quan, Wang Yuan, Han Shuang
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2010 Mar 31;66(Pt 4):m469. doi: 10.1107/S160053681001127X.
Abstract
The Zn(II) atom in the title compound, [ZnCl(2)(C(13)H(20)N(2)O(2))], is four-coordinated by the imine N and phenolate O atoms of the zwitterionic Schiff base ligand, and by two choride ions in a distorted tetra-hedral coordination. In the crystal structure, mol-ecules are linked through inter-molecular N-H⋯O and N-H⋯Cl hydrogen bonds along [010].
摘要
在标题化合物[ZnCl₂(C₁₃H₂₀N₂O₂)]中，Zn(II)原子由两性离子席夫碱配体的亚胺N原子和酚盐O原子以及两个氯离子以扭曲的四面体配位方式进行四配位。在晶体结构中，分子通过沿[010]方向的分子间N—H⋯O和N—H⋯Cl氢键相连。
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