• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

{N'-[(E)-(5-溴-2-氧化苯基亚苄基)苯甲基]苯甲酰肼基}吡啶合镍(II)

{N'-[(E)-(5-Bromo-2-oxidophen-yl)(phen-yl)methyl-ene]benzohydrazidato}pyridine-nickel(II).

作者信息

Zheng Chang-Zheng, Ji Chang-You, Chang Xiu-Li, Zhang Chao-Hua

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 22;65(Pt 8):m965. doi: 10.1107/S1600536809028207.

DOI:10.1107/S1600536809028207
PMID:21583410
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2977364/
Abstract

The asymmetric unit of title complex, [Ni(C(20)H(13)BrN(2)O(2))(C(5)H(5)N)], contains two independent mol-ecules. In each mol-ecule, the central Ni(II) atom has a square-planar environment, formed by the tridentate hydrazone and the monodentate pyridine ligands, with the N atoms in a trans arrangement about the Ni(II) atom.

摘要

标题配合物[Ni(C₂₀H₁₃BrN₂O₂)(C₅H₅N)]的不对称单元包含两个独立分子。在每个分子中，中心Ni(II)原子具有由三齿腙和单齿吡啶配体形成的平面正方形环境，N原子围绕Ni(II)原子呈反式排列。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b8b/2977364/99819f70994d/e-65-0m965-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b8b/2977364/99819f70994d/e-65-0m965-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b8b/2977364/99819f70994d/e-65-0m965-fig1.jpg

相似文献

1
{N'-[(E)-(5-Bromo-2-oxidophen-yl)(phen-yl)methyl-ene]benzohydrazidato}pyridine-nickel(II).{N'-[(E)-(5-溴-2-氧化苯基亚苄基)苯甲基]苯甲酰肼基}吡啶合镍(II)
Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 22;65(Pt 8):m965. doi: 10.1107/S1600536809028207.
2
{N'-[(E)-(5-Bromo-2-oxidophen-yl)(phen-yl)methyl-ene]benzohydrazidato}pyridine-copper(II).{N'-[(E)-(5-溴-2-氧化苯基)(苯基)亚甲基]苯甲酰肼基}吡啶 - 铜(II)
Acta Crystallogr Sect E Struct Rep Online. 2009 Aug 8;65(Pt 9):m1047. doi: 10.1107/S1600536809030463.
3
{N'-[(E)-1-(5-Bromo-2-oxidophen-yl)ethyl-idene-κO]-4-methyl-benzohydrazidato-κN',O}(pyridine-κN)nickel(II).{N'-[(E)-1-(5-溴-2-氧化苯基)亚乙基-κO]-4-甲基苯甲酰肼基-κN',O}(吡啶-κN)镍(II)
Acta Crystallogr Sect E Struct Rep Online. 2011 Aug 1;67(Pt 8):m1132. doi: 10.1107/S1600536811029114. Epub 2011 Jul 23.
4
{N'-[(E)-(5-Bromo-2-oxidophen-yl)(phenyl)-methyl-ene]-4-chloro-benzo-hydrazidato}pyridine-nickel(II).{N'-[(E)-(5-溴-2-氧化苯基)(苯基)亚甲基]-4-氯苯甲酰肼基}吡啶镍(II)
Acta Crystallogr Sect E Struct Rep Online. 2009 Aug 12;65(Pt 9):m1060. doi: 10.1107/S1600536809030943.
5
{N'-[(E)-1-(5-Bromo-2-oxidophen-yl)ethyl-idene]-4-hy-droxy-benzohydrazidato}pyridine-copper(II).{N'-[(E)-1-(5-溴-2-氧化苯基)亚乙基]-4-羟基苯甲酰肼基}吡啶-铜(II)
Acta Crystallogr Sect E Struct Rep Online. 2011 May 1;67(Pt 5):m537. doi: 10.1107/S1600536811011974. Epub 2011 Apr 7.
6
{N'-[(E)-1-(5-Bromo-2-oxidophen-yl)ethyl-idene]-4-chloro-benzohydrazidato}pyridinenickel(II).{N'-[(E)-1-(5-溴-2-氧化苯基)亚乙基]-4-氯苯甲酰肼基}吡啶合镍(II)
Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 20;65(Pt 7):m794. doi: 10.1107/S160053680902234X.
7
Poly[aqua-[μ(2)-cis-1,2-bis-(4-pyrid-yl)ethyl-ene-κN:N'](μ(2)-5-nitro-isophthalato-κO:O',O'')nickel(II)].
Acta Crystallogr Sect E Struct Rep Online. 2009 Dec 19;66(Pt 1):m80-1. doi: 10.1107/S1600536809053872.
8
Bis[μ(2)-1-(2-carb-oxy-benzo-yl)thio-semi-carbazide(3-)]hexa-pyridine-trinickel(II) pyridine monosolvate monohydrate.双[μ(2)-1-(2-羧基苯甲酰基)硫代半卡巴腙(3-)]六吡啶合三镍(II)吡啶单溶剂合物一水合物
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1803. doi: 10.1107/S1600536811048367. Epub 2011 Nov 23.
9
Bis{μ-4-chloro-N'-[(E)-1-(5-chloro-2-oxidophen-yl)ethyl-idene]benzohydrazidato}bis-[pyridine-copper(II)].双{μ-4-氯-N'-[(E)-1-(5-氯-2-氧化苯基)亚乙基]苯甲酰肼基}双[吡啶-铜(II)]。
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1886. doi: 10.1107/S1600536811050720. Epub 2011 Nov 30.
10
Crystal structure of bis-{4-[(4-methyl-benz-yl)-oxy]-'-(4-methyl-benzyl-idene)benzohydrazidato}nickel(II).双-{4-[(4-甲基苄基)-氧基]-(4-甲基亚苄基)苯甲酰肼基}镍(II)的晶体结构
Acta Crystallogr E Crystallogr Commun. 2022 Sep 30;78(Pt 10):1081-1083. doi: 10.1107/S2056989022009392. eCollection 2022 Oct 1.

引用本文的文献

1
{N'-[(E)-(5-Bromo-2-oxidophen-yl)(phen-yl)methyl-ene]benzohydrazidato}pyridine-copper(II).{N'-[(E)-(5-溴-2-氧化苯基)(苯基)亚甲基]苯甲酰肼基}吡啶 - 铜(II)
Acta Crystallogr Sect E Struct Rep Online. 2009 Aug 8;65(Pt 9):m1047. doi: 10.1107/S1600536809030463.

本文引用的文献

1
Hydrazones as analytical reagents: a review.腙类作为分析试剂：综述
Talanta. 1982 Feb;29(2):77-84. doi: 10.1016/0039-9140(82)80024-6.
2
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
3
Antimicrobial and genotoxic activity of 2,6-diacetylpyridine bis(acylhydrazones) and their complexes with some first transition series metal ions. X-ray crystal structure of a dinuclear copper(II) complex.2,6-二乙酰基吡啶双（酰腙）及其与一些第一过渡系金属离子的配合物的抗菌和遗传毒性活性。一种双核铜（II）配合物的X射线晶体结构。
J Inorg Biochem. 1995 Jan;57(1):43-62. doi: 10.1016/0162-0134(94)00004-t.