μ-14,29-二叔丁基-3,10,18,25-四氮杂五环-[25.3.1.1.0.0]三十六-1(31),4,6,8,12(32),14,16,19,21,23,27,29-十二碳烯-31,32-二醇合双[(硝酸根-κO,O')锌(II)]
μ-14,29-Di-tert-butyl-3,10,18,25-tetra-azatpenta-cyclo-[25.3.1.1.0.0]dotriaconta-1(31),4,6,8,12(32),14,16,19,21,23,27,29-dodeca-ene-31,32-diol-ato]bis-[(nitrato-κO,O')zinc(II).
作者信息
Fan Li-Jing, Ma Jian-Fang, Liu Bo
机构信息
Department of Chemistry, Northeast Normal University, Changchun 130024, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 25;65(Pt 8):m985. doi: 10.1107/S1600536809028530.
Abstract
In the title centrosymmetric dinuclear zinc(II) complex, [Zn(2)(C(36)H(42)N(4)O(2))(NO(3))(2)], the Zn(II) atom has a distorted octa-hedral geometry, defined by two N atoms and two O atoms from the macrocyclic ligand and two O atoms from a chelating nitrate anion and are bridged by two phenolate O atoms, forming a four-membered Zn(2)O(2) ring.
摘要
在标题为中心对称双核锌（II）配合物[Zn₂(C₃₆H₄₂N₄O₂)(NO₃)₂]中，锌（II）原子具有扭曲的八面体几何构型，由大环配体的两个氮原子和两个氧原子以及一个螯合硝酸根阴离子的两个氧原子确定，并且由两个酚氧原子桥连，形成一个四元Zn₂O₂环。
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