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1,15:21,35-双（氧二亚乙基）-5,8,11,18,25,28,31,38-八氧杂-1,15,21,35-四氮杂环十四烷-16,20,36,40-四酮-苯（1/2）：一种大环三环四内酰胺。

1,15:21,35-Bis(oxydiethyl-ene)-5,8,11,18,25,28,31,38-octa-oxa-1,15,21,35-tetra-azacyclo-tetra-decane-16,20,36,40-tetra-one-benzene (1/2): a macrotricyclic tetra-lactam.

作者信息

Smith Gary L N, Nguyen Tam, Powell Douglas R, Taylor Richard W

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 18;65(Pt 8):o1927. doi: 10.1107/S1600536809026531.

DOI:10.1107/S1600536809026531
PMID:21583610
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2977422/
Abstract

The macrotricyclic title compound, C(36)H(64)N(4)O(14)·2C(6)H(6), is located on a crystallographic center of symmetry. The mol-ecule has four tertiary amide bridgehead atoms and consists of two unsymmetrical 20-membered diaza-tetra-oxamacrocycles (N(2)O(4) donor atom set) connected through the N atoms by two lateral oxydiethyl-ene bridges. The bridging subunits, together with the short bridging strand (NCCOCCN) from each monocycle, define a 24-membered ring (N(4)O(4) donor atom set) that forms a central cavity.

摘要

大环三环标题化合物C(36)H(64)N(4)O(14)·2C(6)H(6)位于一个晶体学对称中心上。该分子有四个叔酰胺桥头原子，由两个不对称的20元二氮杂四氧杂大环（N(2)O(4)供体原子集）通过两个横向氧二亚乙基桥经由氮原子连接而成。桥连亚基与每个单环的短桥连链段（NCCOCCN）一起定义了一个形成中心腔的24元环（N(4)O(4)供体原子集）。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f36/2977422/6f8bec297388/e-65-o1927-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f36/2977422/58f1e0073b62/e-65-o1927-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f36/2977422/6f8bec297388/e-65-o1927-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f36/2977422/58f1e0073b62/e-65-o1927-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f36/2977422/6f8bec297388/e-65-o1927-fig2.jpg

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本文引用的文献

1
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.