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四氟硼酸双[顺-双-(二苯基膦基)乙烯-κP,P']铜(I)乙醇溶剂合物

Bis[cis-bis-(diphenyl-phosphino)ethene-κP,P']copper(I) tetra-fluoridoborate ethanol solvate.

作者信息

Healy Peter C, Loughrey Bradley T, Williams Michael L

机构信息

Eskitis Institute for Cell and Molecular Therapies, Griffith University, Brisbane 4111, Australia.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Apr 8;65(Pt 5):m500-1. doi: 10.1107/S1600536809012707.

DOI:10.1107/S1600536809012707
PMID:21583749
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2977563/
Abstract

In the title compound [Cu(C(26)H(22)P(2))(2)]BF(4)·C(2)H(5)OH, a disordered ethanol solvate molecule and the anions are located in well defined channels along the c axis. The four-coordinate Cu(P-P)(2) core of the cation adopts approximately D(2) point group symmetry with the Cu-P bond lengths spanning a narrow range from 2.272 (1) to 2.285 (1) Å.

摘要

在标题化合物[Cu(C₂₆H₂₂P₂)₂]BF₄·C₂H₅OH中，一个无序的乙醇溶剂化物分子和阴离子位于沿c轴的明确通道中。阳离子的四配位Cu(P-P)₂核采用近似D₂点群对称性，Cu-P键长在2.272 (1)至2.285 (1) Å的窄范围内。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/46bf/2977563/ff0239fb04ca/e-65-0m500-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/46bf/2977563/d7870717c0e9/e-65-0m500-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/46bf/2977563/ff0239fb04ca/e-65-0m500-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/46bf/2977563/d7870717c0e9/e-65-0m500-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/46bf/2977563/ff0239fb04ca/e-65-0m500-fig2.jpg

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