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(E)-N'-(3,3-二苯基-烯丙叉基)-对甲苯磺酰肼

(E)-N'-(3,3-Diphenyl-allyl-idene)-p-toluene-sulfonohydrazide.

作者信息

Mehrabi Hossein, Kia Reza

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Apr 18;65(Pt 5):o1056. doi: 10.1107/S1600536809013269.

Abstract

In the title compound, C(22)H(20)N(2)O(2)S, the mol-ecule adopts a twisted E configuration around the C=N bond. The two phenyl rings are twisted from each other, making a dihedral angle of 78.00 (12)°. The methyl-substituted benzene ring makes dihedral angles of 32.37 (14) and 69.70 (12)° with the two phenyl rings. In the crystal structure, mol-ecules are linked into extended chains along the b axis through inter-molecular N-H⋯O hydrogen bonds.

摘要

在标题化合物C₂₂H₂₀N₂O₂S中,分子围绕C=N键采取扭曲的E构型。两个苯环相互扭曲,二面角为78.00 (12)°。甲基取代的苯环与两个苯环的二面角分别为32.37 (14)°和69.70 (12)°。在晶体结构中,分子通过分子间N-H⋯O氢键沿b轴连接成延伸链。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b40f/2977737/cd66aae3d58a/e-65-o1056-fig1.jpg

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