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链状聚[[三苯基锡(IV)]-μ(2)-[3-(环己基氨基甲酰基)丙酸根-κO:O]]

catena-Poly[[triphenyl-tin(IV)]-μ(2)-[3-(cyclo-hexyl-carbamo-yl)propanoato-κO:O]].

作者信息

Shams-Ul-Islam S, Bhatti Moazzam H, Ng Seik Weng, Tiekink Edward R T

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 18;66(Pt 10):m1266-7. doi: 10.1107/S1600536810036500.

DOI:10.1107/S1600536810036500
PMID:21587413
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2983217/
Abstract

The Sn atom in the polymeric title compound, Sn(C(6)H(5))(3)(C(10)H(16)NO(3)), is five-coordinated within a trans-C(3)O(2) donor set that defines an approximate trigonal-bipyramidal geometry. The carboxyl-ate ligand is monodentate and the amide O atom bridges a symmetry-related Sn atom, generating a chain along [010] with a linear topology. An intra-molecular carboxyl-ate-carbonyl N-H⋯O hydrogen bond is responsible for the curved conformation within the carboxyl-ate ligand.

摘要

在聚合标题化合物[Sn(C₆H₅)₃(C₁₀H₁₆NO₃)]ₙ中，Sn原子在一个反式-C₃O₂供体组内呈五配位，该供体组定义了一个近似三角双锥几何构型。羧酸根配体为单齿，酰胺O原子桥连一个对称相关的Sn原子，沿[010]方向生成一条具有线性拓扑结构的链。分子内羧酸根-羰基N-H⋯O氢键导致了羧酸根配体内的弯曲构象。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7c25/2983217/74f210d2ee6a/e-66-m1266-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7c25/2983217/e27835b39130/e-66-m1266-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7c25/2983217/74f210d2ee6a/e-66-m1266-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7c25/2983217/e27835b39130/e-66-m1266-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7c25/2983217/74f210d2ee6a/e-66-m1266-fig2.jpg

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本文引用的文献

1
catena-Poly[[triphenyl-tin(IV)]-μ-2-(cyclo-hexyl-amino-carbon-yl)benzoato-κO:O].链状聚[[三苯基锡(IV)]-μ-2-(环己基氨基甲酰基)苯甲酸根-κO:O]
Acta Crystallogr Sect E Struct Rep Online. 2010 Jul 14;66(Pt 8):m931. doi: 10.1107/S1600536810026978.
2
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.