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双{1,4 - 双 - [(3 - 丁基 - 咪唑鎓 - 1 - 基)甲基]苯}-银(I)双(六氟磷酸根)盐

Bis{1,4-bis-[(3-butyl-imidazolium-1-yl)meth-yl]benzene}-silver(I) bis-(hexa-fluoridophosphate).

作者信息

Haque Rosenani A, Washeel Abbas, Teoh Siang Guan, Hemamalini Madhukar, Fun Hoong-Kun

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 25;66(Pt 10):m1286-7. doi: 10.1107/S1600536810036524.

DOI:10.1107/S1600536810036524
PMID:21587429
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2983204/
Abstract

The asymmetric unit of the title complex, Ag(2)(C(22)H(30)N(4))(2)(2), consists of one Ag(I) ion, one 1,4-bis-[(3-butyl-imidazolium-1-yl)meth-yl]benzene ligand and one discrete hexa-fluoridophosphate anion. The formula unit is generated by an inversion center. The unique Ag(I) ion is coordinated by two C atoms of two heterocyclic carbene ligands in an essentially linear geometry. In the crystal structure, cations and anions are linked through weak C-H⋯F hydrogen bonds, forming a three-dimensional network.

摘要

标题配合物Ag(2)(C(22)H(30)N(4))(2)(2)的不对称单元由一个Ag(I)离子、一个1,4-双-[(3-丁基-咪唑鎓-1-基)甲基]苯配体和一个离散的六氟磷酸根阴离子组成。分子式单元由一个倒转中心产生。独特的Ag(I)离子由两个杂环卡宾配体的两个C原子以基本线性的几何构型配位。在晶体结构中，阳离子和阴离子通过弱C-H⋯F氢键相连，形成三维网络。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/81b9/2983204/c65bbcc2feed/e-66-m1286-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/81b9/2983204/cf5a0928cafd/e-66-m1286-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/81b9/2983204/c65bbcc2feed/e-66-m1286-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/81b9/2983204/cf5a0928cafd/e-66-m1286-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/81b9/2983204/c65bbcc2feed/e-66-m1286-fig2.jpg

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本文引用的文献

1
Synthesis and antimicrobial activity of novel Ag-N-hetero-cyclic carbene complexes.新型 Ag-N-杂环卡宾配合物的合成及抗菌活性研究。
Molecules. 2010 Apr 8;15(4):2499-508. doi: 10.3390/molecules15042499.
2
Structure validation in chemical crystallography.化学晶体学中的结构验证
Acta Crystallogr D Biol Crystallogr. 2009 Feb;65(Pt 2):148-55. doi: 10.1107/S090744490804362X. Epub 2009 Jan 20.
3
Anticancer Activity of Ag(I) N-Heterocyclic Carbene Complexes Derived from 4,5-Dichloro-1H-Imidazole.源自4,5-二氯-1H-咪唑的Ag(I) N-杂环卡宾配合物的抗癌活性
Met Based Drugs. 2008;2008:384010. doi: 10.1155/2008/384010.
4
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
5
Ag(I) N-heterocyclic carbene complexes: synthesis, structure, and application.银（I）氮杂环卡宾配合物：合成、结构及应用
Chem Rev. 2005 Nov;105(11):3978-4008. doi: 10.1021/cr050004s.
6
Short metal-metal separations in a highly luminescent trimetallic Ag(I) complex stabilized by bridging NHC ligands.通过桥连NHC配体稳定的高发光三金属Ag(I)配合物中的短金属-金属间距。
Inorg Chem. 2003 Sep 8;42(18):5483-5. doi: 10.1021/ic034483u.