{4,6-双[（E）-1-甲基-2-（吡啶-2-基亚甲基）肼基]嘧啶-κN，N'，N''}二氯化锰（II）
{4,6-Bis[(E)-1-methyl-2-(pyridin-2-yl-methyl-idene)hydrazinyl]pyrimidine-κN,N',N''}dichloridomanganese(II).
作者信息
Marzec Bartosz, Mahimaidoss Mariyatra, Zhang Lei, McCabe Thomas, Schmitt Wolfgang
机构信息
School of Chemistry and CRANN, Trinity College, University of Dublin, College Green, Dublin 2, Republic of Ireland.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1676. doi: 10.1107/S1600536811043352. Epub 2011 Nov 5.
Abstract
In the title compound, [MnCl(2)(C(18)H(18)N(8))], the geometry around the Mn(II) centre is distorted square-pyramidal. In the crystal structure, mol-ecules pack via weak C-H⋯N and C-H⋯Cl inter-actions.
摘要
在标题化合物[MnCl₂(C₁₈H₁₈N₈)]中，Mn(II)中心周围的几何构型为扭曲的四方锥。在晶体结构中，分子通过弱的C—H⋯N和C—H⋯Cl相互作用堆积。
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