Fernandes José A, Gomes Ana C, Figueiredo Sónia, Gago Sandra, Ribeiro-Claro Paulo J A, Gonçalves Isabel S, Almeida Paz Filipe A
Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 26;66(Pt 7):m862-3. doi: 10.1107/S1600536810023950.
In the title compound, (C(5)H(6)N)(3)[MoCl(4)O(2)]Cl, the pyridinium cations are N-H⋯Cl hydrogen bonded to the anionic MoCl(4)O(2) complexes and to the two crystallographically independent chloride anions (located on C2 axes). The Mo(6+) centre adopts a highly distorted octa-hedral geometry, being surrounded by four chloride and two terminal oxide groups. The oxide ligands are mutually cis.
在标题化合物（C₅H₆N）₃[MoCl₄O₂]Cl中，吡啶鎓阳离子通过N-H⋯Cl氢键与阴离子[MoCl₄O₂]²⁻配合物以及两个晶体学独立的氯离子（位于C₂轴上）相连。Mo⁶⁺中心采用高度扭曲的八面体几何构型，被四个氯原子和两个端基氧原子包围。氧配体相互呈顺式。
